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Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones

Enantiopure (R,R) and (S,S)-dimethyl-bis(ethylenedithio)tetrathiafulvalene monosulfones have been synthesized by the aerial oxidation of the chiral dithiolates generated from the propionitrile-protected precursors. Both enantiomers crystallize in the orthorhombic chiral space group P2(1)2(1)2(1). Th...

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Bibliografiske detaljer
Udgivet i:Beilstein J Org Chem
Main Authors: Pop, Flavia, Avarvari, Narcis
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4505188/
https://ncbi.nlm.nih.gov/pubmed/26199666
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.124
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