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Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones
Enantiopure (R,R) and (S,S)-dimethyl-bis(ethylenedithio)tetrathiafulvalene monosulfones have been synthesized by the aerial oxidation of the chiral dithiolates generated from the propionitrile-protected precursors. Both enantiomers crystallize in the orthorhombic chiral space group P2(1)2(1)2(1). Th...
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| Published in: | Beilstein J Org Chem |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
Beilstein-Institut
2015
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4505188/ https://ncbi.nlm.nih.gov/pubmed/26199666 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.124 |
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