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Unprecedented mechanism employed by the Salmonella enterica EutT ATP:Co(I)rrinoid adenosyltransferase precludes adenosylation of incomplete Co(II)rrinoids
Three distinct families of ATP:corrinoid adenosyltransferases (ACATs) exist that are capable of converting vitamin B(12) derivatives to coenzyme B(12) by catalyzing the thermodynamically challenging reduction of Co(II)rrinoids to form “super-nucleophilic” Co(I) intermediates. While the structures an...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4504680/ https://ncbi.nlm.nih.gov/pubmed/25914129 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501930 |
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