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A Simple and Highly Effective Ligand System for the Copper(I)-Mediated Assembly of Rotaxanes**
A [2]rotaxane was produced through the assembly of a picolinaldehyde, an amine, and a bipyridine macrocycle around a Cu(I) template by imine bond formation in close-to-quantitative yield. An analogous [3]rotaxane is obtained in excellent yield by replacing the amine with a diamine, thus showing the...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
WILEY-VCH Verlag
2014
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4502974/ https://ncbi.nlm.nih.gov/pubmed/25314000 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201407817 |
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