Reactions in Nitroimidazole Triggered by Low-Energy (0–2 eV) Electrons: Methylation at N1-H Completely Blocks Reactivity**

Low-energy electrons (LEEs) at energies of less than 2 eV effectively decompose 4-nitroimidazole (4NI) by dissociative electron attachment (DEA). The reactions include simple bond cleavages but also complex reactions involving multiple bond cleavages and formation of new molecules. Both simple and c...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Tanzer, Katrin, Feketeová, Linda, Puschnigg, Benjamin, Scheier, Paul, Illenberger, Eugen, Denifl, Stephan
Médium: Artigo
Jazyk:Inglês
Vydáno: WILEY-VCH Verlag 2014
Témata:
Communications
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4501305/
https://ncbi.nlm.nih.gov/pubmed/25224248
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201407452
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