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Synthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines

A novel gold-catalyzed divergent sysnthesis of furans and pyrroles employing readily available homopropargylic aldehydes and imines have been developed. The regiochemical outcome of this reaction is dependent on the substituent on the terminal alkyne of substrate. Thus, substrates possessing alkyl a...

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Bibliografiset tiedot
Julkaisussa:Tetrahedron Lett
Päätekijät: Shiroodi, Roohollah Kazem, Vera, Claudia I. Rivera, Dudnik, Alexander S., Gevorgyan, Vladimir
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2015
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4500526/
https://ncbi.nlm.nih.gov/pubmed/26185336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.01.006
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