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Conformational effects and stereocontrol in synthesis studies of medium-ring dolabellane carbocycles
Stereoselective reactions are described which lead to functionalization of the dolabellane skeleton. The stereoselectivity is attributed to conformational effects imposed by the eleven-membered ring. An efficient pathway provides for the stereocontrolled synthesis of nonracemic 6(S)-hydroxy-4(E)-dol...
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| Publicado no: | Tetrahedron Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4484730/ https://ncbi.nlm.nih.gov/pubmed/26139943 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.049 |
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