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Role of Protons in Superoxide Reduction by a Superoxide Reductase Analogue
Superoxide reduction by thiolate-ligated [Fe(II)(S(Me2)N(4)(tren))](+) (1) involves two proton-dependent steps and a single peroxide intermediate, [Fe(III)(S(Me2)N(4)(tren))(OOH)](+) (2). An external proton donor is required, ruling out mechanisms involving H(+) or H-atom abstraction from the ligand...
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| Publicado en: | Inorg Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2005
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4484572/ https://ncbi.nlm.nih.gov/pubmed/15732947 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic048818z |
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