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Selective Oxidation of Benzylic and Allylic Alcohols Using Mn(OAc)(3)/Catalytic 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone
A practical, chemoselective oxidation of alcohols employing catalytic quantities of DDQ as the oxidant and Mn(OAc)(3) as the co-oxidant is described. Electron–rich benzylic alcohols are oxidized efficiently to their corresponding carbonyls, but less electron–rich benzylic alcohols remain unchanged....
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4482348/ https://ncbi.nlm.nih.gov/pubmed/21395252 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200441g |
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