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Surprisingly Facile C–H Activation in the Course of Oxime-Directed Catalytic Asymmetric Hydroboration

Deuterium-labeling studies carried out in conjunction with investigations into the directed catalytic asymmetric hydroboration of unsaturated oxime ethers reveal a surprisingly facile ortho-metallation or σ-bond metathesis pathway that that diverts the expected course of CAHB to a tandem C-H activat...

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Detalhes bibliográficos
Publicado no:Tetrahedron Lett
Main Authors: Thacker, Nathan C., Shoba, Veronika M., Geis, Andrew E., Takacs, James M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4480785/
https://ncbi.nlm.nih.gov/pubmed/26120214
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.076
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