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Enantioselective synthesis of metacycloprodigiosin via the “Wasserman pyrrole”

A concise, nine-step enantioselective total synthesis of metacycloprodigiosin is reported. The synthesis provides increased step-efficiency over the previous racemic and enantioselective syntheses of this compound. Key features of the work include investigations into a convergent oxidative coupling...

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Publicado en:Tetrahedron Lett
Autores principales: Vega, Marvin M., Crain, Diana M., Konkol, Leah C., Thomson, Regan J.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2014
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4480779/
https://ncbi.nlm.nih.gov/pubmed/26120213
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.075
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