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Transformation of [M+2H](2+) Peptide Cations to [M-H](+), [M+H+O](+), and M(+•) Cations via Ion/Ion Reactions: Reagent Anions Derived from Persulfate
The gas-phase oxidation of doubly protonated peptides is demonstrated here using ion/ion reactions with a suite of reagents derived from persulfate. Intact persulfate anion (HS(2)O(8)(−)), peroxymonosulfate anion (HSO(5)(−)), and sulfate radical anions (SO(4)(−•)) are all either observed directly up...
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| Publicado no: | J Am Soc Mass Spectrom |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4475491/ https://ncbi.nlm.nih.gov/pubmed/25944366 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-015-1125-y |
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