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Ion/Ion Reactions with “Onium” Reagents: An Approach for the Gas-phase Transfer of Organic Cations to Multiply-Charged Anions

The use of ion/ion reactions to effect gas-phase alkylation is demonstrated. Commonly used fixed-charge “onium” cations are well-suited for ion/ion reactions with multiply deprotonated analytes because of their tendency to form long-lived electrostatic complexes. Activation of these complexes result...

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Detalhes bibliográficos
Publicado no:J Am Soc Mass Spectrom
Main Authors: Gilbert, Joshua D., Prentice, Boone M., McLuckey, Scott A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4654941/
https://ncbi.nlm.nih.gov/pubmed/25652935
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-015-1077-2
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