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Ruthenium(0) Catalyzed Endiyne-α-Ketol [4+2] Cycloaddition: Convergent Assembly of Type II Polyketide Substructures via C-C Bond Forming Transfer Hydrogenation
Upon exposure of 3,4-benzannulated 1,5-diynes (benzo-endiynes) to α-ketols (α-hydroxyketones) in the presence of ruthenium(0) catalysts derived from Ru(3)(CO)(12) and RuPhos or CyJohnPhos, successive redox-triggered C-C coupling occurs to generate products of [4+2] cycloaddition. The proposed cataly...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4470559/ https://ncbi.nlm.nih.gov/pubmed/25938947 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b02755 |
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