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Alternative Synthesis and Structures of C-monoacetylenic Phosphaalkenes
An alternative synthesis of C-monoacetylenic phosphaalkenes trans-Mes*P=C(Me)(C≡CR) (Mes* = 2, 4, 6-(t)Bu(3)Ph, R = Ph, SiMe(3)) from C-bromophosphaalkenes cis-Mes*P=C(Me)Br using standard Sonogashira coupling conditions is described. Crystallographic studies confirm cis-trans isomerization of the P...
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| Publicado no: | Z Anorg Allg Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
WILEY-VCH Verlag
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4456767/ https://ncbi.nlm.nih.gov/pubmed/26063932 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/zaac.201200324 |
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