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Palladium(II)-catalyzed Highly Enantioselective C–H Arylation of Cyclopropylmethylamines
Highly enantioselective (up to 99.5% ee) arylation of cyclopropyl C–H bonds with aryl iodides has been developed using a chiral Pd(II) catalyst. Mono-protected amino acid ligands (MPAA) are demonstrated to be compatible with one of the most extensively studied C–H arylation reactions through a Pd(II...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4433166/ https://ncbi.nlm.nih.gov/pubmed/25581489 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512529e |
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