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The Fenton oxidation mechanism: reactivities of biologically relevant substrates with two oxidizing intermediates differ from those predicted for the hydroxyl radical.

The application of kinetic probes that allow one to determine relative reactivities of biologically relevant substrates with oxidizing intermediates in the Fenton reagent (H2O2 plus Fe2+ in acidic aqueous solution) is described. These results lead to the conclusion that there are two key intermediat...

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Detalhes bibliográficos
Main Authors: Wink, D A, Nims, R W, Saavedra, J E, Utermahlen, W E, Ford, P C
Formato: Artigo
Idioma:Inglês
Publicado em: 1994
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC44251/
https://ncbi.nlm.nih.gov/pubmed/8022825
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