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Dehydrogenation at the Energetic Limit of β-Hydride Elimination
Alcohol is the Answer! Ruthenium(II) complexes catalyze the C-C coupling of 1,1-disubstituted allenes and fluorinated alcohols to form homoallylic alcohols bearing all-carbon quaternary centers with good to complete levels of diastereoselectivity. Whereas fluorinated alcohols are relatively abundant...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4405479/ https://ncbi.nlm.nih.gov/pubmed/25757459 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201500238 |
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