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Distinguishing gramicidin D conformers through two-dimensional infrared spectroscopy of vibrational excitons

Gramicidin D is a short peptide which dimerizes to form helical pores, adopting one of two conformations in the process. These conformations differ primarily in number of residues per turn and the hydrogen-bond registry between rungs of the helix. Using amide I 2D infrared (IR) and FTIR, we have dem...

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Detalhes bibliográficos
Publicado no:J Chem Phys
Main Authors: Stevenson, Paul, Tokmakoff, Andrei
Formato: Artigo
Idioma:Inglês
Publicado em: AIP Publishing LLC 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4401804/
https://ncbi.nlm.nih.gov/pubmed/26049444
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4917321
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