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Zero-strain reductive intercalation in a molecular framework

Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycli...

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Detalhes bibliográficos
Publicado no:CrystEngComm
Main Authors: Hill, Joshua A., Cairns, Andrew B., Lim, Jared J. K., Cassidy, Simon J., Clarke, Simon J., Goodwin, Andrew L.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4396389/
https://ncbi.nlm.nih.gov/pubmed/25892969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4ce02364a
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