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Ferryl Protonation in Oxoiron(IV) Porphyrins and Its Role in Oxygen Transfer
[Image: see text] Ferryl porphyrins, P−Fe(IV)=O, are central reactive intermediates in the catalytic cycles of numerous heme proteins and a variety of model systems. There has been considerable interest in elucidating factors, such as terminal oxo basicity, that may control ferryl reactivity. Here,...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4363944/ https://ncbi.nlm.nih.gov/pubmed/25651467 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508759t |
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