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Four-Step Synthesis of the Antimalarial Cardamom Peroxide via an Oxygen Stitching Strategy
[Image: see text] A four-step synthesis of the antimalarial terpene cardamom peroxide, a 1,2-dioxepane-containing natural product, is reported from (−)-myrtenal and molecular oxygen. This highly concise route was guided by biosynthetic logic and enabled by an unusual manganese-catalyzed, tandem hydr...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4353017/ https://ncbi.nlm.nih.gov/pubmed/24673099 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja502208z |
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