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Adaptation of a Small-Molecule Hydrogen-Bond Donor Catalyst to an Enantioselective Hetero-Diels–Alder Reaction Hypothesized for Brevianamide Biosynthesis

[Image: see text] Chiral diamine-derived hydrogen-bond donors were evaluated for their ability to effect stereocontrol in an intramolecular hetero-Diels–Alder (HDA) reaction hypothesized in the biosynthesis of brevianamides A and B. Collectively, these results provide proof of principle that small-m...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Sprague, Daniel J., Nugent, Benjamin M., Yoder, Ryan A., Vara, Brandon A., Johnston, Jeffrey N.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4339957/
https://ncbi.nlm.nih.gov/pubmed/25697748
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503626w
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