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Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family

We report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH(2)-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specif...

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Bibliografiske detaljer
Udgivet i:CrystEngComm
Main Authors: Serra-Crespo, Pablo, Dikhtiarenko, Alla, Stavitski, Eli, Juan-Alcañiz, Jana, Kapteijn, Freek, Coudert, François-Xavier, Gascon, Jorge
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4338503/
https://ncbi.nlm.nih.gov/pubmed/25722647
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4CE00436A
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