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Molecular promoting of aluminium metal-organic framework topology MIL-101 by N,N - dimethylformamide
In-situ NMR and DFT modelling demonstrate that N,N-dimethylformamide (DMF) promotes the formation of metal-organic framework NH(2)-MIL-101(Al). In-situ NMR studies show that upon dissociation of an aluminium-coordinated aqua ligand in NH(2)-MOF-235(Al), DMF forms an HCl-DMF complex during synthesis....
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| Autori principali: | , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2014
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4051174/ https://ncbi.nlm.nih.gov/pubmed/24405155 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic402198a |
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