Molecular promoting of aluminium metal-organic framework topology MIL-101 by N,N - dimethylformamide

In-situ NMR and DFT modelling demonstrate that N,N-dimethylformamide (DMF) promotes the formation of metal-organic framework NH(2)-MIL-101(Al). In-situ NMR studies show that upon dissociation of an aluminium-coordinated aqua ligand in NH(2)-MOF-235(Al), DMF forms an HCl-DMF complex during synthesis....

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Detaylı Bibliyografya
Asıl Yazarlar: Goesten, Maarten G., Magusin, Pieter C.M.M, Pidko, Evgeny A., Mezari, Brahim, Hensen, Emiel J.M., Kapteijn, Freek, Gascon, Jorge
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2014
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Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4051174/
https://ncbi.nlm.nih.gov/pubmed/24405155
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic402198a
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