Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. Structure and Properties of Bis[o-xylyldithiolato-μ(2)-sulfidoferrate(III)], an Analog of the 2Fe-2S Proteins

The synthetic analog approach has been applied to a clarification of the active sites of 2Fe-2S(*) proteins. The compound (Et(4)N)(2)[FeS(SCH(2))(2)C(6)H(4)](2), derived from o-xylyl-α,α′-dithiol, has been prepared and its structure has been determined by x-ray diffraction. The centrosymmetric anion...

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Publicat a:	Proc Natl Acad Sci U S A
Autors principals:	Mayerle, J. J., Frankel, R. B., Holm, R. H., Ibers, James A., Phillips, W. D., Weiher, J. F.
Format:	Artigo
Idioma:	Inglês
Publicat:	National Academy of Sciences 1973
Matèries:	Physical Sciences: Chemistry
Accés en línia:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC433750/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/4525429/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.70.8.2429
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