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Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. Structure and Properties of Bis[o-xylyldithiolato-μ(2)-sulfidoferrate(III)], an Analog of the 2Fe-2S Proteins
The synthetic analog approach has been applied to a clarification of the active sites of 2Fe-2S(*) proteins. The compound (Et(4)N)(2)[FeS(SCH(2))(2)C(6)H(4)](2), derived from o-xylyl-α,α′-dithiol, has been prepared and its structure has been determined by x-ray diffraction. The centrosymmetric anion...
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| Publicado no: | Proc Natl Acad Sci U S A |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1973
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC433750/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/4525429/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.70.8.2429 |
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