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Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. Structure and Properties of Bis[o-xylyldithiolato-μ(2)-sulfidoferrate(III)], an Analog of the 2Fe-2S Proteins

The synthetic analog approach has been applied to a clarification of the active sites of 2Fe-2S(*) proteins. The compound (Et(4)N)(2)[FeS(SCH(2))(2)C(6)H(4)](2), derived from o-xylyl-α,α′-dithiol, has been prepared and its structure has been determined by x-ray diffraction. The centrosymmetric anion...

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Detalhes bibliográficos
Main Authors: Mayerle, J. J., Frankel, R. B., Holm, R. H., Ibers, James A., Phillips, W. D., Weiher, J. F.
Formato: Artigo
Idioma:Inglês
Publicado em: 1973
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC433750/
https://ncbi.nlm.nih.gov/pubmed/4525429
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