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Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids from a common intermediate through regiocontrolled cyclizations by Staudinger reactions

Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids bearing distinctive core structures were achieved through Staudinger reactions using a common intermediate. In the key cyclization step, water functioned like a switch to control which core structure to produce. The chemistry...

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Detalhes bibliográficos
Publicado no:Org Chem Front
Main Authors: Li, Zining, Geng, Qian, Lv, Zhe, Pritchett, Beau P., Baba, Katsuaki, Numajiri, Yoshitaka, Stoltz, Brian M., Liang, Guangxin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4333676/
https://ncbi.nlm.nih.gov/pubmed/25717379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4qo00312h
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