Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit.

To complete the set of synthetic analogs of the three recognized types of active sites in iron-sulfur redox proteins, the compound (Et4N)[Fe((SCH2)2C6H4)2], derived from o-xylyl-alpha,alpha'-dithiol, has been prepared and its structure has been determined by x-ray diffraction. The bischelate an...

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Bibliographic Details
Published in:Proc Natl Acad Sci U S A
Main Authors: Lane, R W, Ibers, J A, Frankel, R B, Holm, R H
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 1975
Subjects:
Research Article
Online Access:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC432878/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/1059080/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.72.8.2868
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