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Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit.

To complete the set of synthetic analogs of the three recognized types of active sites in iron-sulfur redox proteins, the compound (Et4N)[Fe((SCH2)2C6H4)2], derived from o-xylyl-alpha,alpha'-dithiol, has been prepared and its structure has been determined by x-ray diffraction. The bischelate an...

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Main Authors: Lane, R W, Ibers, J A, Frankel, R B, Holm, R H
格式: Artigo
語言:Inglês
出版: 1975
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC432878/
https://ncbi.nlm.nih.gov/pubmed/1059080
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