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The Acid-Base Properties, Hydrolytic Mechanism, and Susceptibility to O(2) Oxidation of Fe(4)S(4)(SR)(4)(-2) Clusters
The iron-sulfur cluster compounds Fe(4)S(4)(SR)(4)(-2) [where —SR = —SCH(3), —S—C(CH(3))(3), and —S— CH(2)—CH(CH(3))(2)] have been found to represent the base species of weak acids of pK(a) comparable to that of carboxylic acids. The acid species Fe(4)S(4)(SR)(4)H(-) is most subject to reaction with...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
1975
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC432277/ https://ncbi.nlm.nih.gov/pubmed/16592211 |
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