Model for “charge-relay”: Acceleration by carboxylate anion in intramolecular general base-catalyzed ester hydrolysis by the imidazolyl group
The effect of benzoate anion on intramolecular general base-catalyzed ester hydrolysis by the imidazolyl group in endo-5-[4′(5′)-imidazolyl]bicyclo[2.2.1]hept-endo-2-yl trans-cinnamate was examined in dioxane/H(2)O solutions. Benzoate anion exhibited a remarkable acceleration of the intramolecular g...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1977
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC431221/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/19738/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.74.7.2634 |
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