Model for “charge-relay”: Acceleration by carboxylate anion in intramolecular general base-catalyzed ester hydrolysis by the imidazolyl group

The effect of benzoate anion on intramolecular general base-catalyzed ester hydrolysis by the imidazolyl group in endo-5-[4′(5′)-imidazolyl]bicyclo[2.2.1]hept-endo-2-yl trans-cinnamate was examined in dioxane/H(2)O solutions. Benzoate anion exhibited a remarkable acceleration of the intramolecular g...

Täydet tiedot

Bibliografiset tiedot

Julkaisussa:	Proc Natl Acad Sci U S A
Päätekijät:	Komiyama, Makoto, Bender, Myron L., Utaka, Masanori, Takeda, Akira
Aineistotyyppi:	Artigo
Kieli:	Inglês
Julkaistu:	National Academy of Sciences 1977
Aiheet:	Physical Sciences: Chemistry
Linkit:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC431221/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/19738/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.74.7.2634
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