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The Direct α-Arylation of Ethers via the Merger of Photoredox Mediated C–H Functionalization and the Minisci Reaction()

The direct α-arylation of cyclic and acyclic ethers with heteroarenes has been accomplished via the design of a new photoredox mediated C–H functionalization pathway. Transiently generated α-oxyalkyl radicals, produced from a variety of widely available ethers via hydrogen atom transfer (HAT), were...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Jin, Jian, MacMillan, David W. C.
Format: Artigo
Language:Inglês
Published: 2014
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4311771/
https://ncbi.nlm.nih.gov/pubmed/25470570
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201410432
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