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Rh(I)–Bisphosphine-Catalyzed Asymmetric, Intermolecular Hydroheteroarylation of α-Substituted Acrylate Derivatives

[Image: see text] Asymmetric hydroheteroarylation of alkenes represents a convenient entry to elaborated heterocyclic motifs. While chiral acids are known to mediate asymmetric addition of electron-rich heteroarenes to Michael acceptors, very few methods exploit transition metals to catalyze alkylat...

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Publicat a:J Am Chem Soc
Autors principals: Filloux, Claire M., Rovis, Tomislav
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4304441/
https://ncbi.nlm.nih.gov/pubmed/25545834
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja511445x
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