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N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of α-Proteo and Deutero α-Chloro and α-Fluoro Carboxylic Acids
[Image: see text] Asymmetric hydration of α,α-dichloro aldehydes and α-halo enals via a NHC-catalyzed redox process to yield enantioenriched α-chloro and α-fluoro carboxylic acids is described herein. The developed reaction allows for installation of an α-deuterium to give rise to enantioenriched α-...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2010
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2839412/ https://ncbi.nlm.nih.gov/pubmed/20151675 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910281s |
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