Electrophile-Integrating Smiles Rearrangement Provides Previously Inaccessible C4′-O-Alkyl Heptamethine Cyanine Fluorophores

[Image: see text] New synthetic methods to rapidly access useful fluorophores are needed to advance modern molecular imaging techniques. A new variant of the classical Smiles rearrangement is reported that enables the efficient synthesis of previously inaccessible C4′-O-alkyl heptamethine cyanines....

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Bibliographic Details
Published in:Org Lett
Main Authors: Nani, Roger R., Shaum, James B., Gorka, Alexander P., Schnermann, Martin J.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2015
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4301176/
https://ncbi.nlm.nih.gov/pubmed/25562683
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503398f
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