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Enantioselective Oxidative Gold Catalysis Enabled by a Designed Chiral P,N-Bidentate Ligand
A newly developed P,N-bidentate ligand enables enantioselective intramolecular cyclopropanations by in-situ generated, reactive α-oxo gold carbene intermediate. The ligand design is based on our previously proposed structure of the carbene intermediate in the presence of a P,N-bidentate ligand, whic...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4300284/ https://ncbi.nlm.nih.gov/pubmed/25431180 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201409300 |
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