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The reaction of an iridium PNP complex with parahydrogen facilitates polarisation transfer without chemical change
The short lived pincer complex [(C(5)H(3)N(CH(2)P((t)Bu)(2))(2))Ir(H)(2)(py)]BF(4) is shown to be active for signal amplification by reversible exchange. This catalyst formulation enables the efficient transfer of polarization from parahydrogen to be placed into just a single molecule of the hyperpo...
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| Publicado no: | Dalton Trans |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4295814/ https://ncbi.nlm.nih.gov/pubmed/25410259 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4dt03088e |
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