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Mechanistic insights into hydroacylation with non-chelating aldehydes

The combination of a small-bite-angle diphosphine bis(dicyclohexylphosphino)methane (dcpm) and [Rh(cod)OMe](2) catalyses the hydroacylation of 2-vinylphenols with a wide range of non-chelating aldehydes. Here we present a detailed experimental study that elucidates the factors contributing to the br...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Murphy, Stephen K., Bruch, Achim, Dong, Vy M.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4285142/
https://ncbi.nlm.nih.gov/pubmed/25580215
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02026j
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