A Combined Experimental and Computational Investigation on the Unusual Molecular Mechanism of the Lossen Rearrangement Reaction Activated by Carcinogenic Halogenated Quinones

[Image: see text] The classic Lossen rearrangement is a well-known reaction describing the transformation of an O-activated hydroxamic acid into the corresponding isocyanate. In this study, we found that chlorinated benzoquinones (C(n)BQ) serve as a new class of agents for the activation of benzohyd...

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Bibliographic Details
Published in:J Org Chem
Main Authors: Shan, Guo-Qiang, Yu, Ao, Zhao, Chuan-Fang, Huang, Chun-Hua, Zhu, Ling-Yan, Zhu, Ben-Zhan
Format: Artigo
Language:Inglês
Published: American Chemical Society 2014
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4285140/
https://ncbi.nlm.nih.gov/pubmed/25470188
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo5022713
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