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A Combined Experimental and Computational Investigation on the Unusual Molecular Mechanism of the Lossen Rearrangement Reaction Activated by Carcinogenic Halogenated Quinones
[Image: see text] The classic Lossen rearrangement is a well-known reaction describing the transformation of an O-activated hydroxamic acid into the corresponding isocyanate. In this study, we found that chlorinated benzoquinones (C(n)BQ) serve as a new class of agents for the activation of benzohyd...
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Publicado no: | J Org Chem |
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Main Authors: | , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
American Chemical
Society
2014
|
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4285140/ https://ncbi.nlm.nih.gov/pubmed/25470188 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo5022713 |
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