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A Biomimetic Strategy to Access the Silybins: Total Synthesis of (−)-Isosilybin A
[Image: see text] We report the first asymmetric, total synthesis of (−)-isosilybin A. A late-stage catalytic biomimetic cyclization of a highly functionalized chalcone is employed to form the characteristic benzopyranone ring. A robust and flexible approach to this chalcone provides an entry to the...
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| 出版年: | Org Lett |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical Society
2014
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| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4284651/ https://ncbi.nlm.nih.gov/pubmed/25517432 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503303w |
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