Water Oxidation Catalysis by Co(II) Impurities in Co(III)(4)O(4) Cubanes

[Image: see text] The observed water oxidation activity of the compound class Co(4)O(4)(OAc)(4)(Py–X)(4) emanates from a Co(II) impurity. This impurity is oxidized to produce the well-known Co-OEC heterogeneous cobaltate catalyst, which is an active water oxidation catalyst. We present results from...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Am Chem Soc
Prif Awduron: Ullman, Andrew M., Liu, Yi, Huynh, Michael, Bediako, D. Kwabena, Wang, Hongsen, Anderson, Bryce L., Powers, David C., Breen, John J., Abruña, Héctor D., Nocera, Daniel G.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: American Chemical Society 2014
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC4277775/
https://ncbi.nlm.nih.gov/pubmed/25407218
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5110393
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