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Rhodium-Catalyzed N–H Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2-Picolylamines and Imidazo[1,2-a]pyridines
A general and efficient N–H insertion reaction of rhodium pyridyl carbenes derived from pyridotriazoles was developed. Various N–H containing compounds, including amides, anilines, enamine and aliphatic amines, smoothly underwent the N–H insertion reaction to afford 2-picolylamine derivatives. The d...
Sparad:
| I publikationen: | Angew Chem Int Ed Engl |
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| Huvudupphovsmän: | , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2014
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4262672/ https://ncbi.nlm.nih.gov/pubmed/25332116 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201408335 |
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