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Rhodium-Catalyzed N–H Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2-Picolylamines and Imidazo[1,2-a]pyridines
A general and efficient N–H insertion reaction of rhodium pyridyl carbenes derived from pyridotriazoles was developed. Various N–H containing compounds, including amides, anilines, enamine and aliphatic amines, smoothly underwent the N–H insertion reaction to afford 2-picolylamine derivatives. The d...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4262672/ https://ncbi.nlm.nih.gov/pubmed/25332116 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201408335 |
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