A Catalytic Borylation/Dehalogenation Route to o-Fluoro Arylboronates

[Image: see text] A two-step Ir-catalyzed borylation/Pd-catalyzed dehalogenation sequence allows for the net synthesis of fluoroarenes where the boronic ester is ortho to fluorine. Key elements of this approach include the use of a halogen para to the fluorine to block meta Ir-catalyzed borylation a...

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Bibliografske podrobnosti
izdano v:Org Lett
Main Authors: Jayasundara, Chathurika R. K., Unold, Jason M., Oppenheimer, Jossian, Smith, Milton R., Maleczka, Robert E.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4260632/
https://ncbi.nlm.nih.gov/pubmed/25418716
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5028738
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