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Irreversible Catalyst Activation Enables Hyperpolarization and Water Solubility for NMR Signal Amplification by Reversible Exchange

[Image: see text] Activation of a catalyst [IrCl(COD)(IMes)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; COD = cyclooctadiene)] for signal amplification by reversible exchange (SABRE) was monitored by in situ hyperpolarized proton NMR at 9.4 T. During the catalyst-activation process, t...

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Foilsithe in:J Phys Chem B
Main Authors: Truong, Milton L., Shi, Fan, He, Ping, Yuan, Bingxin, Plunkett, Kyle N., Coffey, Aaron M., Shchepin, Roman V., Barskiy, Danila A., Kovtunov, Kirill V., Koptyug, Igor V., Waddell, Kevin W., Goodson, Boyd M., Chekmenev, Eduard Y.
Formáid: Artigo
Teanga:Inglês
Foilsithe: American Chemical Society 2014
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4259498/
https://ncbi.nlm.nih.gov/pubmed/25372972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp510825b
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