Irreversible Catalyst Activation Enables Hyperpolarization and Water Solubility for NMR Signal Amplification by Reversible Exchange

[Image: see text] Activation of a catalyst [IrCl(COD)(IMes)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; COD = cyclooctadiene)] for signal amplification by reversible exchange (SABRE) was monitored by in situ hyperpolarized proton NMR at 9.4 T. During the catalyst-activation process, t...

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Detalhes bibliográficos
Publicado no:J Phys Chem B
Main Authors: Truong, Milton L., Shi, Fan, He, Ping, Yuan, Bingxin, Plunkett, Kyle N., Coffey, Aaron M., Shchepin, Roman V., Barskiy, Danila A., Kovtunov, Kirill V., Koptyug, Igor V., Waddell, Kevin W., Goodson, Boyd M., Chekmenev, Eduard Y.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4259498/
https://ncbi.nlm.nih.gov/pubmed/25372972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp510825b
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