Irreversible Catalyst Activation Enables Hyperpolarization and Water Solubility for NMR Signal Amplification by Reversible Exchange

[Image: see text] Activation of a catalyst [IrCl(COD)(IMes)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; COD = cyclooctadiene)] for signal amplification by reversible exchange (SABRE) was monitored by in situ hyperpolarized proton NMR at 9.4 T. During the catalyst-activation process, t...

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Publicado en:J Phys Chem B
Main Authors: Truong, Milton L., Shi, Fan, He, Ping, Yuan, Bingxin, Plunkett, Kyle N., Coffey, Aaron M., Shchepin, Roman V., Barskiy, Danila A., Kovtunov, Kirill V., Koptyug, Igor V., Waddell, Kevin W., Goodson, Boyd M., Chekmenev, Eduard Y.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2014
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4259498/
https://ncbi.nlm.nih.gov/pubmed/25372972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp510825b
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